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Issue 73, 2015
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Mismatched changes of the photoluminescence and crystalline structure of a mechanochromic gold(I) isocyanide complex

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Abstract

The mechanochromic compound 1 forms green-emitting crystals (1g) and blue-emitting crystals (1b) that exhibit two intriguing responses to mechanical stimulation. Upon mechanical stimulation, the emission color of 1g does not change but its crystalline structure does. Conversely, 1b shows a clear emission shift, but it retains its molecular arrangement upon grinding.

Graphical abstract: Mismatched changes of the photoluminescence and crystalline structure of a mechanochromic gold(i) isocyanide complex

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Publication details

The article was received on 04 Jun 2015, accepted on 23 Jul 2015 and first published on 23 Jul 2015


Article type: Communication
DOI: 10.1039/C5CC04609B
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2015,51, 13933-13936
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    Mismatched changes of the photoluminescence and crystalline structure of a mechanochromic gold(I) isocyanide complex

    T. Seki, K. Sakurada and H. Ito, Chem. Commun., 2015, 51, 13933
    DOI: 10.1039/C5CC04609B

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