Jump to main content
Jump to site search

Issue 58, 2015
Previous Article Next Article

High surface area and Z′ in a thermally stable 8-fold polycatenated hydrogen-bonded framework

Author affiliations

Abstract

1,3,5-Tris(4-carboxyphenyl)benzene assembles into an intricate 8-fold polycatenated assembly of (6,3) hexagonal nets formed through hydrogen bonds and π-stacking. One polymorph features 56 independent molecules in the asymmetric unit, the largest Z′ reported to date. The framework is permanently porous, with a BET surface area of 1095 m2 g−1 and readily adsorbs N2, H2 and CO2.

Graphical abstract: High surface area and Z′ in a thermally stable 8-fold polycatenated hydrogen-bonded framework

Back to tab navigation

Supplementary files

Publication details

The article was received on 21 May 2015, accepted on 15 Jun 2015 and first published on 16 Jun 2015


Article type: Communication
DOI: 10.1039/C5CC04219D
Citation: Chem. Commun., 2015,51, 11642-11645
  •   Request permissions

    High surface area and Z′ in a thermally stable 8-fold polycatenated hydrogen-bonded framework

    C. A. Zentner, H. W. H. Lai, J. T. Greenfield, R. A. Wiscons, M. Zeller, C. F. Campana, O. Talu, S. A. FitzGerald and J. L. C. Rowsell, Chem. Commun., 2015, 51, 11642
    DOI: 10.1039/C5CC04219D

Search articles by author

Spotlight

Advertisements