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Issue 61, 2015
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Stabilization of cubic Sr2FeMoO6 through topochemical reduction

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Abstract

Sr2FeMoO6 has been extensively studied for application in spintronic devices. Through the topochemical de-intercalation of oxygen anions with metal hydride reduction, we demonstrate that the high temperature cubic phase is stabilized, at room temperature, whilst leaving the magnetic ordering intact. Synchrotron X-ray and neutron powder diffraction were used to characterize the structure and stoichiometry of the reduced oxide.

Graphical abstract: Stabilization of cubic Sr2FeMoO6 through topochemical reduction

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Publication details

The article was received on 19 May 2015, accepted on 25 Jun 2015 and first published on 01 Jul 2015


Article type: Communication
DOI: 10.1039/C5CC04145G
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2015,51, 12201-12204
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    Stabilization of cubic Sr2FeMoO6 through topochemical reduction

    D. D. Taylor, N. J. Schreiber, C. M. Brown, A. M. Arevalo-Lopez and E. E. Rodriguez, Chem. Commun., 2015, 51, 12201
    DOI: 10.1039/C5CC04145G

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