Issue 50, 2015

Peptoid nanosheets as soluble, two-dimensional templates for calcium carbonate mineralization

Abstract

Nacre-mimetic materials are of great interest, but difficult to synthesize, because they require the ordering of organic and inorganic materials on several length scales. Here we introduce peptoid nanosheets as a versatile two-dimensional platform to develop nacre mimetic materials. Free-floating zwitterionic nanosheets were mineralized with thin films of amorphous calcium carbonate (of 2–20 nm thickness) on their surface to produce planar nacre synthons. These can serve as tunable building blocks to produce layered brick and mortar nanoarchitectures.

Graphical abstract: Peptoid nanosheets as soluble, two-dimensional templates for calcium carbonate mineralization

Supplementary files

Article information

Article type
Communication
Submitted
22 Apr 2015
Accepted
21 May 2015
First published
21 May 2015

Chem. Commun., 2015,51, 10218-10221

Author version available

Peptoid nanosheets as soluble, two-dimensional templates for calcium carbonate mineralization

J. M. V. Jun, M. V. P. Altoe, S. Aloni and R. N. Zuckermann, Chem. Commun., 2015, 51, 10218 DOI: 10.1039/C5CC03323C

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