Azo-functionalized microporous organic polymers: synthesis and applications in CO2 capture and conversion

Zhenzhen Yang; Hongye Zhang; Bo Yu; Yanfei Zhao; Zhishuang Ma; Guipeng Ji; Buxing Han; Zhimin Liu

doi:10.1039/C5CC03151F

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Azo-functionalized microporous organic polymers: synthesis and applications in CO₂ capture and conversion†

Zhenzhen Yang,^a Hongye Zhang,^a Bo Yu,^a Yanfei Zhao,^a Zhishuang Ma,^a Guipeng Ji,^a Buxing Han^a and Zhimin Liu*^a

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* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: liuzm@iccas.ac.cn

Abstract

Azo-functionalized MOPs (Azo-MOPs) were synthesized via oxidative polymerization of aromatic amines catalyzed by t-BuOCl/NaI (25 °C, 1 h, yield: >95%), which displayed an excellent coordinating ability with a Ru complex. The resulting Ru-coordinated Azo-MOPs displayed high CO₂ capacity and high performances for catalyzing the methylation of amines with CO₂ under low pressure (0.5 MPa).

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Article information

DOI: https://doi.org/10.1039/C5CC03151F
Article type: Communication
Submitted: 16 Apr 2015
Accepted: 10 Jun 2015
First published: 10 Jun 2015

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Chem. Commun., 2015,51, 11576-11579

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Azo-functionalized microporous organic polymers: synthesis and applications in CO₂ capture and conversion

Z. Yang, H. Zhang, B. Yu, Y. Zhao, Z. Ma, G. Ji, B. Han and Z. Liu, Chem. Commun., 2015, 51, 11576 DOI: 10.1039/C5CC03151F

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Chemical Communications