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Issue 47, 2015
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Copper(I)-catalyzed carbon–halogen bond-selective boryl substitution of alkyl halides bearing terminal alkene moieties

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Abstract

The selective boryl substitution of alkyl halides bearing terminal C[double bond, length as m-dash]C double bonds has been achieved using a copper(I)/tricyclohexylphosphine or copper(I)/o-diphenylphosphinophenol catalyst. This reaction represents a useful complementary approach to conventional procedures for the hydroboration of C[double bond, length as m-dash]C double bonds or the borylative cyclization of alkyl halides bearing terminal alkenes.

Graphical abstract: Copper(i)-catalyzed carbon–halogen bond-selective boryl substitution of alkyl halides bearing terminal alkene moieties

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Publication details

The article was received on 02 Apr 2015, accepted on 05 May 2015 and first published on 05 May 2015


Article type: Communication
DOI: 10.1039/C5CC02760H
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2015,51, 9655-9658
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    Copper(I)-catalyzed carbon–halogen bond-selective boryl substitution of alkyl halides bearing terminal alkene moieties

    H. Iwamoto, K. Kubota, E. Yamamoto and H. Ito, Chem. Commun., 2015, 51, 9655
    DOI: 10.1039/C5CC02760H

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