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Issue 50, 2015
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Direct accessibility of mixed-metal (III/II) acid sites through the rational synthesis of porous metal carboxylates

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Abstract

The scalable and environmentally-friendly synthesis of mixed Fe(III)/M(II) (M = Ni, Co, Mg) polycarboxylate porous MOFs based on the Secondary Building Unit approach is reported. A combination of in situ infrared spectroscopy, 57Fe Mössbauer spectrometry and adsorption microcalorimetry confirms the direct accessibility of the iron(III) and metal(II) sites under low temperature activation conditions.

Graphical abstract: Direct accessibility of mixed-metal (iii/ii) acid sites through the rational synthesis of porous metal carboxylates

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Publication details

The article was received on 27 Mar 2015, accepted on 14 May 2015 and first published on 14 May 2015


Article type: Communication
DOI: 10.1039/C5CC02550H
Citation: Chem. Commun., 2015,51, 10194-10197
  • Open access: Creative Commons BY-NC license
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    Direct accessibility of mixed-metal (III/II) acid sites through the rational synthesis of porous metal carboxylates

    S. Wongsakulphasatch, F. Nouar, J. Rodriguez, L. Scott, C. Le Guillouzer, T. Devic, P. Horcajada, J.-M. Grenèche, P. L. Llewellyn, A. Vimont, G. Clet, M. Daturi and C. Serre, Chem. Commun., 2015, 51, 10194
    DOI: 10.1039/C5CC02550H

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