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Issue 42, 2015
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Tuning radical reactivity using iodine in oxidative C(sp3)–H/C(sp)–H cross-coupling: an easy way toward the synthesis of furans and indolizines

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Abstract

Molecular iodine was found to be an effective redox catalyst for the oxidative cross-coupling of carbonyl compounds with terminal alkynes. In this work, we demonstrated that iodine could tune radical reactivity through reversible C–I bond formation for controlling the reaction selectivity. This iodine catalysis protocol provided an easy way for the synthesis of various furans and indolizines.

Graphical abstract: Tuning radical reactivity using iodine in oxidative C(sp3)–H/C(sp)–H cross-coupling: an easy way toward the synthesis of furans and indolizines

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Publication details

The article was received on 03 Mar 2015, accepted on 17 Apr 2015 and first published on 17 Apr 2015


Article type: Communication
DOI: 10.1039/C5CC01825K
Citation: Chem. Commun., 2015,51, 8769-8772
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    Tuning radical reactivity using iodine in oxidative C(sp3)–H/C(sp)–H cross-coupling: an easy way toward the synthesis of furans and indolizines

    S. Tang, K. Liu, Y. Long, X. Qi, Y. Lan and A. Lei, Chem. Commun., 2015, 51, 8769
    DOI: 10.1039/C5CC01825K

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