Issue 33, 2015
From the journal:

Chemical Communications

Reversible and contrasting changes of the cloud point temperature of pillar[5]arenes with one quinone unit and tri(ethylene oxide) chains induced by redox chemistry and host–guest complexation†

Tomoki Ogoshi,*a   Tomohiro Akutsu,a   Yuko Tamuraa  and  Tada-aki Yamagishia  

* Corresponding authors

a Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa, Japan
E-mail: ogoshi@se.kanazawa-u.ac.jp

Abstract

A new water-soluble redox-active pillar[5]arene was synthesized by incorporation of one benzoquinone unit. The pillar[5]arene showed redox-responsive reversible lower critical solution temperature changes in aqueous solution.

Graphical abstract: Reversible and contrasting changes of the cloud point temperature of pillar[5]arenes with one quinone unit and tri(ethylene oxide) chains induced by redox chemistry and host–guest complexation

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Article information

DOI
https://doi.org/10.1039/C5CC01630D
Article type
Communication
Submitted
24 Feb 2015
Accepted
17 Mar 2015
First published
20 Mar 2015

Chem. Commun., 2015,51, 7184-7186

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Reversible and contrasting changes of the cloud point temperature of pillar[5]arenes with one quinone unit and tri(ethylene oxide) chains induced by redox chemistry and host–guest complexation

T. Ogoshi, T. Akutsu, Y. Tamura and T. Yamagishi, Chem. Commun., 2015, 51, 7184 DOI: 10.1039/C5CC01630D

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