Issue 54, 2015
From the journal:

Chemical Communications

Heterobimetallic complexes with redox-active mesoionic carbenes as metalloligands: electrochemical properties, electronic structures and catalysis†

Lara Hettmanczyk,a   Sinja Manck,a   Carolin Hoyer,a   Stephan Hohlocha  and  Biprajit Sarkar*a  

* Corresponding authors

a Institut für Chemie und Biochemie, Freie Universität Berlin, Fabeckstraße 34-36, Berlin, Germany
E-mail: biprajit.sarkar@fu-berlin.de
Tel: +493083850919

Abstract

A mesoionic carbene with a ferrocene backbone is used as a metalloligand to generate the first example of their Fe–Au heterobimetallic complexes. The details of geometric and electronic structures in different redox states and preliminary catalytic results are presented.

Graphical abstract: Heterobimetallic complexes with redox-active mesoionic carbenes as metalloligands: electrochemical properties, electronic structures and catalysis

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Article information

DOI
https://doi.org/10.1039/C5CC01578B
Article type
Communication
Submitted
21 Feb 2015
Accepted
28 May 2015
First published
28 May 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 10949-10952

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Heterobimetallic complexes with redox-active mesoionic carbenes as metalloligands: electrochemical properties, electronic structures and catalysis

L. Hettmanczyk, S. Manck, C. Hoyer, S. Hohloch and B. Sarkar, Chem. Commun., 2015, 51, 10949 DOI: 10.1039/C5CC01578B

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