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Issue 46, 2015
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Oxocentered Cu(II) lead selenite honeycomb lattices hosting Cu(I)Cl2 groups obtained by chemical vapor transport reactions

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Abstract

Chemical vapor transport (CVT) reactions were used to prepare three modular mixed-valent Cu(I)–Cu(II) compounds, (Pb2Cu2+9O4)(SeO3)4(Cu+Cl2)Cl5 (1), (PbCu2+5O2)(SeO3)2(Cu+Cl2)Cl3 (2), and (PbxCu2+(6−x)O2)(SeO3)2(Cu+Cl2)K(1−x)Cl(4−x) (x = 0.20) (3). In their crystal structures chains of anion-centered (OCu2+4) and (OCu2+3Pb) tetrahedra form honeycomb-like double layers with cavities occupied by linear [Cu+Cl2] groups.

Graphical abstract: Oxocentered Cu(ii) lead selenite honeycomb lattices hosting Cu(i)Cl2 groups obtained by chemical vapor transport reactions

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Publication details

The article was received on 15 Feb 2015, accepted on 30 Apr 2015 and first published on 01 May 2015


Article type: Communication
DOI: 10.1039/C5CC01426C
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2015,51, 9563-9566
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    Oxocentered Cu(II) lead selenite honeycomb lattices hosting Cu(I)Cl2 groups obtained by chemical vapor transport reactions

    V. M. Kovrugin, M. Colmont, O. I. Siidra, O. Mentré, A. Al-Shuray, V. V. Gurzhiy and S. V. Krivovichev, Chem. Commun., 2015, 51, 9563
    DOI: 10.1039/C5CC01426C

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