Issue 46, 2015
From the journal:

Chemical Communications

Iron-catalyzed aerobic C–H functionalization of pyrrolones†

Li-wei Liu,a   Zhen-zhen Wang,a   Hui-hui Zhang,a   Wan-shu Wang,a   Ji-zong Zhanga  and  Yu Tang*a  

* Corresponding authors

a School of Pharmaceutical Science and Technology, Key Laboratory for Modern Drug Delivery & High-Efficiency, Tianjin University, Tianjin, P. R. China
E-mail: yutang@tju.edu.cn

Abstract

The aerobic oxidation of pyrrolones catalyzed by Fe(OTf)3 to form reactive N-acyliminium ion intermediates that undergo nucleophilic additions with alcohols to give the corresponding products in moderate to good yields is described.

Graphical abstract: Iron-catalyzed aerobic C–H functionalization of pyrrolones

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Article information

DOI
https://doi.org/10.1039/C5CC01425E
Article type
Communication
Submitted
15 Feb 2015
Accepted
17 Apr 2015
First published
17 Apr 2015

Chem. Commun., 2015,51, 9531-9534

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Iron-catalyzed aerobic C–H functionalization of pyrrolones

L. Liu, Z. Wang, H. Zhang, W. Wang, J. Zhang and Y. Tang, Chem. Commun., 2015, 51, 9531 DOI: 10.1039/C5CC01425E

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