Issue 29, 2015
From the journal:

Chemical Communications

Copper-mediated ortho C–H sulfonylation of benzoic acid derivatives with sodium sulfinates†

Jidan Liu,a   Lin Yu,a   Shaobo Zhuang,a   Qingwen Gui,a   Xiang Chen,a   Wenduo Wanga  and  Ze Tan*a  

* Corresponding authors

a State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China
E-mail: ztanze@gmail.com

Abstract

Copper-mediated direct ortho C–H bond sulfonylation of benzoic acid derivatives with sodium sulfinates was achieved by employing an 8-aminoquinoline moiety as the bidentate directing group. Various aryl sulfones were synthesized in good yields with excellent regioselectivity.

Graphical abstract: Copper-mediated ortho C–H sulfonylation of benzoic acid derivatives with sodium sulfinates

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Article information

DOI
https://doi.org/10.1039/C5CC00202H
Article type
Communication
Submitted
09 Jan 2015
Accepted
06 Mar 2015
First published
06 Mar 2015

Chem. Commun., 2015,51, 6418-6421

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Copper-mediated ortho C–H sulfonylation of benzoic acid derivatives with sodium sulfinates

J. Liu, L. Yu, S. Zhuang, Q. Gui, X. Chen, W. Wang and Z. Tan, Chem. Commun., 2015, 51, 6418 DOI: 10.1039/C5CC00202H

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