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Issue 31, 2015
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9,9′-Anthryl-anthroxyl radicals: strategic stabilization of highly reactive phenoxyl radicals

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Abstract

Stable 9,9′-anthryl-anthroxyl radicals were synthesized and isolated, and the structures were fully characterized by single crystal X-ray diffraction analysis and ESR measurement. The resonance structure and steric protection of the peripheral positions and the most reactive 9-position of anthracene prolong the half-life of the radical in solution to 11 days.

Graphical abstract: 9,9′-Anthryl-anthroxyl radicals: strategic stabilization of highly reactive phenoxyl radicals

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Publication details

The article was received on 18 Dec 2014, accepted on 27 Jan 2015 and first published on 13 Feb 2015


Article type: Communication
DOI: 10.1039/C4CC10104A
Citation: Chem. Commun., 2015,51, 6734-6737
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    9,9′-Anthryl-anthroxyl radicals: strategic stabilization of highly reactive phenoxyl radicals

    T. Aotake, M. Suzuki, N. Aratani, J. Yuasa, D. Kuzuhara, H. Hayashi, H. Nakano, T. Kawai, J. Wu and H. Yamada, Chem. Commun., 2015, 51, 6734
    DOI: 10.1039/C4CC10104A

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