Issue 18, 2015
From the journal:

Chemical Communications

Bonding situation in Be[N(SiMe3)2]2 – an experimental and computational study†

D. Naglav,a   A. Neumann,a   D. Bläser,a   C. Wölper,a   R. Haack,a   G. Jansena  and  S. Schulz*a  

* Corresponding authors

a University of Duisburg-Essen, Universitätsstr. 5-7, S07 S03 C30, 45117 Essen, Germany
E-mail: stephan.schulz@uni-due.de
Fax: +49 201 1833830
Tel: +49 201 1834635

Abstract

The solid state structure of Be[N(SiMe3)2]2 (1) was determined by in situ crystallisation and the bonding situation investigated by quantum chemical calculations. The Be–N bond is predominantly ionic, but some evidence for the presence of a partial Be–N double bond character was found.

Graphical abstract: Bonding situation in Be[N(SiMe3)2]2 – an experimental and computational study

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Article information

DOI
https://doi.org/10.1039/C4CC09732G
Article type
Communication
Submitted
05 Dec 2014
Accepted
29 Jan 2015
First published
30 Jan 2015
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 3889-3891

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Bonding situation in Be[N(SiMe3)2]2 – an experimental and computational study

D. Naglav, A. Neumann, D. Bläser, C. Wölper, R. Haack, G. Jansen and S. Schulz, Chem. Commun., 2015, 51, 3889 DOI: 10.1039/C4CC09732G

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