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Issue 3, 2015
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Frustrated Lewis pair behavior of monomeric (boryl)iminomethanes accessed from isocyanide 1,1-hydroboration

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Abstract

The activation of carbon dioxide, organonitriles, and terminal acetylenes by (boryl)iminomethanes derived from isocyanide 1,1-hydroboration is described. Also detailed is the generality of hydroboration of m-terphenylisocyanides with hydroboranes of differing Lewis acidities.

Graphical abstract: Frustrated Lewis pair behavior of monomeric (boryl)iminomethanes accessed from isocyanide 1,1-hydroboration

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The article was received on 11 Oct 2014, accepted on 07 Nov 2014 and first published on 10 Nov 2014


Article type: Communication
DOI: 10.1039/C4CC08037H
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2015,51, 541-544
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    Frustrated Lewis pair behavior of monomeric (boryl)iminomethanes accessed from isocyanide 1,1-hydroboration

    B. R. Barnett, C. E. Moore, A. L. Rheingold and J. S. Figueroa, Chem. Commun., 2015, 51, 541
    DOI: 10.1039/C4CC08037H

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