Issue 27, 2015

Dynamic stereoisomerization in inherently chiral bimetallic [2]catenanes

Abstract

Stereoisomerization and the unprecedented phenomenon of metal translocation in the absence of redox processes were probed in two inherently chiral bimetallic [2]catenanes by using a combination of variable-temperature 1H NMR and CD spectroscopies, X-ray crystallography, and DFT calculations.

Graphical abstract: Dynamic stereoisomerization in inherently chiral bimetallic [2]catenanes

Supplementary files

Article information

Article type
Communication
Submitted
18 Sep 2014
Accepted
18 Nov 2014
First published
19 Nov 2014

Chem. Commun., 2015,51, 5840-5843

Dynamic stereoisomerization in inherently chiral bimetallic [2]catenanes

T. Prakasam, M. Lusi, E. Nauha, J. Olsen, M. Sy, C. Platas-Iglesias, L. J. Charbonnière and A. Trabolsi, Chem. Commun., 2015, 51, 5840 DOI: 10.1039/C4CC07392D

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