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Issue 4, 2015
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A colorimetric method of analysis for trace amounts of hydrogen peroxide with the use of the nano-properties of molybdenum disulfide

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Abstract

Molybdenum disulfide (MoS2) is an emerging material with some unique physical and electronic properties somewhat comparable to those of graphene. It was prepared with the use of a simple hydrothermal process, and has a layered structure similar to that of graphene. Also, it has a peroxidase-like catalytic activity and is able to catalyze the oxidation of the colorless peroxidase substrate, 3,3′,5,5′-tetramethylbenzidine (TMB), in the presence of H2O2 to produce a blue product. This reaction used MoS2 as a useful peroxidase, which involved a colorimetric method for trace analysis of H2O2 in water, e.g. lake waters. This method is uncomplicated, inexpensive and highly sensitive for H2O2 in the 0.125–1.75 μM range (LOD: 0.08 μM). It is also quite stable in the presence of many common inorganic and organic potentially interfering compounds, e.g. metal ions as well as amino acids and sugars.

Graphical abstract: A colorimetric method of analysis for trace amounts of hydrogen peroxide with the use of the nano-properties of molybdenum disulfide

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Publication details

The article was received on 25 Oct 2014, accepted on 11 Dec 2014 and first published on 12 Dec 2014


Article type: Paper
DOI: 10.1039/C4AN01950D
Author version available: Download Author version (PDF)
Citation: Analyst, 2015,140, 1119-1126
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    A colorimetric method of analysis for trace amounts of hydrogen peroxide with the use of the nano-properties of molybdenum disulfide

    X. Guo, Y. Wang, F. Wu, Y. Ni and S. Kokot, Analyst, 2015, 140, 1119
    DOI: 10.1039/C4AN01950D

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