Issue 28, 2014

Ultrafast chemical dynamic behavior in highly epitaxial LaBaCo2O5+δ thin films

Abstract

The redox reactions of highly epitaxial LaBaCo2O5+δ (LBCO) thin films exposed to the switching flow of reducing (H2) and oxidizing (O2) gases were examined at various temperatures between 260 and 700 °C. Their electrical resistance was measured using a precise ac bridge measurement system. The as-grown LBCO films have very good electrical conductivity at low and medium temperatures between 400 and 700 °C, and are extremely sensitive to reducing and oxidizing environments with superfast redox dynamics. The LBCO thin films show more complex redox reactions at low temperatures (300–350 °C), suggesting the occurrence of conducting-to-insulating-to-conducting transitions during the redox reactions. In particular, the insulating-to-conducting transition under an oxidation process is superfast, with the largest resistance change of up to 3 × 107 Ω s−1, occurring even at a low temperature of 300 °C. The extremely short response time, the giant resistance change, and the excellent chemical stability in a broad temperature range from 260 to 700 °C suggests that the highly epitaxial LBCO thin-films can be excellent candidates for low-temperature solid oxide fuel cells, chemical sensors, and catalyst applications.

Graphical abstract: Ultrafast chemical dynamic behavior in highly epitaxial LaBaCo2O5+δ thin films

Article information

Article type
Paper
Submitted
12 Mar 2014
Accepted
24 Apr 2014
First published
24 Apr 2014

J. Mater. Chem. C, 2014,2, 5660-5666

Author version available

Ultrafast chemical dynamic behavior in highly epitaxial LaBaCo2O5+δ thin films

H. B. Wang, S. Y. Bao, J. Liu, G. Collins, C. R. Ma, M. Liu, C. L. Chen, C. Dong, M.-H. Whangbo, H. M. Guo and H. J. Gao, J. Mater. Chem. C, 2014, 2, 5660 DOI: 10.1039/C4TC00492B

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