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Issue 10, 2014
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Submerged liquid plasma – low energy synthesis of nitrogen-doped graphene for electrochemical applications

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Abstract

In this study, micro-plasma discharge is produced by applying a high electric potential between graphite and Pt electrodes in acetonitrile solvent. The electrons generated in the micro-plasma discharge collide with acetonitrile and produce ˙H and ˙CH2CN radicals. The radicalized graphene layer exfoliated from the graphite electrode reacts with nascent hydrogen (˙H) and acetonitrile (˙CH2CN) radicals and partially restores its aromaticity and conjugation. Raman spectra of the product confirm the synthesis of nitrogen-functionalized graphene (N-FG), which has a marginal increase in disorderness compared to that of pure graphite and remarkable dispersibility in both hydrophilic and hydrophobic solvents. The excellent fluorescence properties of N-FG confirm the presence of fluorophores such as –NH and –N[double bond, length as m-dash]C– at the radicalized graphene sites, as supported by ultraviolet-visible spectroscopy and X-ray photoelectron spectroscopy studies. The functional groups present in N-FG lead to excellent electrochemical performance, with distinct redox peaks in cyclic voltammetry and a high specific capacitance of 291 F g−1 at a scan rate of 5 mV s−1. N-FG exhibits excellent cycling stability, with a marginal reduction of specific capacitance (<10% reduction) at the end of 1000 cycles.

Graphical abstract: Submerged liquid plasma – low energy synthesis of nitrogen-doped graphene for electrochemical applications

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Publication details

The article was received on 28 Nov 2013, accepted on 23 Dec 2013 and first published on 02 Jan 2014


Article type: Paper
DOI: 10.1039/C3TA14946C
Citation: J. Mater. Chem. A, 2014,2, 3332-3337
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    Submerged liquid plasma – low energy synthesis of nitrogen-doped graphene for electrochemical applications

    J. Senthilnathan, K. S. Rao and M. Yoshimura, J. Mater. Chem. A, 2014, 2, 3332
    DOI: 10.1039/C3TA14946C

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