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Issue 9, 2014
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Green synthesis of polyvinyl alcohol (PVA)–cellulose nanofibril (CNF) hybrid aerogels and their use as superabsorbents

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Abstract

Cross-linked polyvinyl alcohol (PVA)–cellulose nanofibril (CNF) hybrid organic aerogels were prepared using an environmentally friendly freeze-drying process. The resulting PVA/CNF aerogel was rendered both superhydrophobic and superoleophilic after being treated with methyltrichlorosilane via a simple thermal chemical vapor deposition process. Successful silanization on the surface of the porous aerogel was confirmed by various techniques including scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDS), Fourier transform infrared spectroscopy (FTIR), and contact angle measurements. The silane-treated, cross-linked PVA/CNF aerogels not only exhibited excellent absorption performance for various types of oils (e.g., crude oil) or organic solvents (with a typical weight gain ranging from 44 to 96 times of their own dry weight), but also showed a remarkable scavenging capability for several types of heavy metal ions tested (e.g., Pb2+, Hg2+), making them versatile absorbents for various potential applications including water purification. Furthermore, these PVA/CNF aerogels demonstrated excellent elasticity and mechanical durability after silane-treatment as evidenced by the cyclic compression tests.

Graphical abstract: Green synthesis of polyvinyl alcohol (PVA)–cellulose nanofibril (CNF) hybrid aerogels and their use as superabsorbents

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Publication details

The article was received on 12 Nov 2013, accepted on 16 Dec 2013 and first published on 16 Dec 2013


Article type: Paper
DOI: 10.1039/C3TA14642A
Author version available: Download Author version (PDF)
Citation: J. Mater. Chem. A, 2014,2, 3110-3118
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    Green synthesis of polyvinyl alcohol (PVA)–cellulose nanofibril (CNF) hybrid aerogels and their use as superabsorbents

    Q. Zheng, Z. Cai and S. Gong, J. Mater. Chem. A, 2014, 2, 3110
    DOI: 10.1039/C3TA14642A

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