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Ultrafast structural dynamics in Rydberg excited N,N,N′,N′-tetramethylethylenediamine: conformation dependent electron lone pair interaction and charge delocalization

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a
Department of Chemistry, Brown University, Providence, USA
E-mail: peter_weber@brown.edu;
Fax: +1-401-8632594 ;
Tel: +1-401-8633767
b
Department of Chemistry, Duke University, Durham, USA
c
Linac Coherent Light Source (LCLS), SLAC National Accelerator Laboratory, Menlo Park, USA
d
Faculty of Physical Sciences, University of Iceland, VR-III, 107 Reykjavík, Iceland
Chem. Sci., 2014,5, 4394-4403

DOI: 10.1039/C4SC01646G
Received 04 Jun 2014, Accepted 15 Jul 2014
First published online 16 Jul 2014
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