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Issue 9, 2014
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An organic cation as a silver(I) analogue for the arylation of sp2 and sp3 C–H bonds with iodoarenes

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Abstract

Reactions promoted by stoichiometric amounts of silver salts suffer from high cost, limited availability and raise environmental concerns. This manuscript describes studies leading to the discovery of a general replacement for silver with an inexpensive and convenient organic salt in palladium catalyzed direct C(sp2)–H and C(sp3)–H arylation reactions.

Graphical abstract: An organic cation as a silver(i) analogue for the arylation of sp2 and sp3 C–H bonds with iodoarenes

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Publication details

The article was received on 27 Apr 2014, accepted on 04 Jun 2014 and first published on 26 Jun 2014


Article type: Edge Article
DOI: 10.1039/C4SC01215A
Citation: Chem. Sci., 2014,5, 3509-3514
  • Open access: Creative Commons BY license
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    An organic cation as a silver(I) analogue for the arylation of sp2 and sp3 C–H bonds with iodoarenes

    C. Arroniz, J. G. Denis, A. Ironmonger, G. Rassias and I. Larrosa, Chem. Sci., 2014, 5, 3509
    DOI: 10.1039/C4SC01215A

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