Issue 37, 2014
From the journal:

RSC Advances

Pd/C-catalyzed cross-coupling reaction of benzyloxysilanes with halosilanes for selective synthesis of unsymmetrical siloxanes†

Masayasu Igarashi,a   Keiko Kubo,a   Tomohiro Matsumoto,a   Kazuhiko Sato,a   Wataru Andoa  and  Shigeru Shimada*a  

* Corresponding authors

a National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan
E-mail: s-shimada@aist.go.jp
Fax: +81-298-61-4568
Tel: +81-298-61-6257

Abstract

A new protocol for the nonhydrolytic synthesis of unsymmetrical siloxanes has been developed. The cross-coupling reaction of benzyloxysilanes with halosilanes catalyzed by Pd/C afforded various unsymmetrical siloxanes with co-production of benzyl halides.

Graphical abstract: Pd/C-catalyzed cross-coupling reaction of benzyloxysilanes with halosilanes for selective synthesis of unsymmetrical siloxanes

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Article information

DOI
https://doi.org/10.1039/C4RA02126F
Article type
Communication
Submitted
11 Mar 2014
Accepted
11 Apr 2014
First published
11 Apr 2014

RSC Adv., 2014,4, 19099-19102

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Pd/C-catalyzed cross-coupling reaction of benzyloxysilanes with halosilanes for selective synthesis of unsymmetrical siloxanes

M. Igarashi, K. Kubo, T. Matsumoto, K. Sato, W. Ando and S. Shimada, RSC Adv., 2014, 4, 19099 DOI: 10.1039/C4RA02126F

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