Issue 26, 2014
From the journal:

RSC Advances

Ammonium formate as a green hydrogen source for clean semi-continuous enzymatic dynamic kinetic resolution of (+/−)-α-methylbenzylamine

Amanda S. de Miranda,a   Rodrigo O. M. A. de Souzaa  and  Leandro S. M. Miranda*a  

* Corresponding authors

a Federal University of Rio de Janeiro, Biocatalysis and Organic Synthesis Lab, Chemistry Institute, Av athos da Silveira Ramos, Rio de Janeiro, Brazil
E-mail: leandrosoter@iq.ufrj.br

Abstract

The chemoenzymatic dynamic kinetic resolution of (+/−)-α-methylbenzylamine under continuous flow conditions in the presence of Pd/BaSO4 as racemization catalyst and ammonium formate as reductant is described. Under the conditions good conversions and excellent enantiomeric excess are reported.

Graphical abstract: Ammonium formate as a green hydrogen source for clean semi-continuous enzymatic dynamic kinetic resolution of (+/−)-α-methylbenzylamine

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Article information

DOI
https://doi.org/10.1039/C4RA00462K
Article type
Paper
Submitted
16 Jan 2014
Accepted
26 Feb 2014
First published
12 Mar 2014

RSC Adv., 2014,4, 13620-13625

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Ammonium formate as a green hydrogen source for clean semi-continuous enzymatic dynamic kinetic resolution of (+/−)-α-methylbenzylamine

A. S. de Miranda, R. O. M. A. de Souza and L. S. M. Miranda, RSC Adv., 2014, 4, 13620 DOI: 10.1039/C4RA00462K

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