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Issue 86, 2014
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Immobilization of helicene onto carbon substrates through electropolymerization of [7]helicenyl-thiophene

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Abstract

In this work, monomeric 3-([7]helicen-9-yl)thiophene was synthesized and used for the preparation of a polymeric film by electrosynthesis. The polymer prepared was characterized using Fe(CN)63−/4− and Ru(NH3)63+/2+ redox probes, scanning electron microscopy and vibrational spectroscopy. The electropolymerization approach presented here provides a new option for the immobilization of helicenes onto solid supports.

Graphical abstract: Immobilization of helicene onto carbon substrates through electropolymerization of [7]helicenyl-thiophene

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Publication details

The article was received on 26 Jun 2014, accepted on 16 Sep 2014 and first published on 16 Sep 2014


Article type: Communication
DOI: 10.1039/C4RA06283C
Citation: RSC Adv., 2014,4, 46102-46105
  • Open access: Creative Commons BY license
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    Immobilization of helicene onto carbon substrates through electropolymerization of [7]helicenyl-thiophene

    J. Hrbac, J. Storch, V. Halouzka, V. Cirkva, P. Matejka and J. Vacek, RSC Adv., 2014, 4, 46102
    DOI: 10.1039/C4RA06283C

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