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Issue 49, 2014
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Novel green fatty acid-based bis-cyclic carbonates for the synthesis of isocyanate-free poly(hydroxyurethane amide)s

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Abstract

Fatty acid-based bis-cyclic 5-membered carbonates containing amide linkages were prepared from methyl 10-undecenoate. The reaction in bulk of these bio-based carbonates with a series of di-amines led to poly(hydroxyurethane amide)s with molar masses up to 31 000 g mol−1. As expected, the so-formed bio-based thermoplastic poly(hydroxyurethane)s exhibit amorphous to semi-crystalline features with respect to the chemical structure of the monomers used.

Graphical abstract: Novel green fatty acid-based bis-cyclic carbonates for the synthesis of isocyanate-free poly(hydroxyurethane amide)s

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Publication details

The article was received on 22 Apr 2014, accepted on 03 Jun 2014 and first published on 03 Jun 2014


Article type: Paper
DOI: 10.1039/C4RA03675A
Author version available: Download Author version (PDF)
Citation: RSC Adv., 2014,4, 25795-25803
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    Novel green fatty acid-based bis-cyclic carbonates for the synthesis of isocyanate-free poly(hydroxyurethane amide)s

    L. Maisonneuve, A. S. More, S. Foltran, C. Alfos, F. Robert, Y. Landais, T. Tassaing, E. Grau and H. Cramail, RSC Adv., 2014, 4, 25795
    DOI: 10.1039/C4RA03675A

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