A regio- and stereo-controlled, one-pot amidoglycosylation of alcohols has been achieved using O-acetylated glycals, trichloroethoxysulfonamide, and iodosobenzene in the presence of a rhodium(II) catalyst. The reaction would proceed via stereoselective intermolecular aziridination of the glycal.
The article was received on 18 Mar 2014, accepted on 23 Apr 2014 and first published on 25 Apr 2014
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