Issue 37, 2014

Palladium-catalyzed desulfitative C–P coupling of arylsulfinate metal salts and H-phosphonates

Abstract

Catalyzed by palladium(II) chloride, a diverse range of arylsulfinate sodium, potassium, lithium, silver, zinc, and copper salts undergo desulfination/C–P coupling with H-phosphonates, in the presence of silver(I) carbonate as oxidant, to produce useful arylphosphonates under microwave irradiation.

Graphical abstract: Palladium-catalyzed desulfitative C–P coupling of arylsulfinate metal salts and H-phosphonates

Supplementary files

Article information

Article type
Communication
Submitted
13 Feb 2014
Accepted
14 Apr 2014
First published
14 Apr 2014

RSC Adv., 2014,4, 19214-19217

Author version available

Palladium-catalyzed desulfitative C–P coupling of arylsulfinate metal salts and H-phosphonates

J. Li, X. Bi, H. Wang and J. Xiao, RSC Adv., 2014, 4, 19214 DOI: 10.1039/C4RA01270D

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