Issue 14, 2014
From the journal:

RSC Advances

DMAP-promoted multicomponent reaction of cyanoacetylene, MBH carbonate and water: a facile access to functional quaternary carbon†

Ling-Guo Meng,a   Chun-Tao Li,a   Jin-Feng Zhang,a   Guo-Yuan Xiaoa  and  Lei Wang*ab  

* Corresponding authors

a Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P.R. China
E-mail: leiwang@chnu.edu.cn
Fax: +86-561-309-0518
Tel: +86-561-380-2069

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P.R. China

Abstract

An efficient method for the synthesis of highly functionalized products containing cyanide-substituted quaternary carbon centers via DMAP-promoted multicomponent reactions of cyanoacetylene, Morita–Baylis–Hillman (MBH) carbonate and water was developed. The reactions could be achieved under simple and mild conditions.

Graphical abstract: DMAP-promoted multicomponent reaction of cyanoacetylene, MBH carbonate and water: a facile access to functional quaternary carbon

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Article information

DOI
https://doi.org/10.1039/C3RA47105E
Article type
Communication
Submitted
27 Nov 2013
Accepted
06 Jan 2014
First published
07 Jan 2014

RSC Adv., 2014,4, 7109-7111

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DMAP-promoted multicomponent reaction of cyanoacetylene, MBH carbonate and water: a facile access to functional quaternary carbon

L. Meng, C. Li, J. Zhang, G. Xiao and L. Wang, RSC Adv., 2014, 4, 7109 DOI: 10.1039/C3RA47105E

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