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Issue 1, 2014
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Quantification of ion binding using electrospray mass spectrometry

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Abstract

Mass spectrometry has predominately been used as a qualitative tool in the analysis of complexes with quantitative studies being difficult to validate. Here, we present a method where electrospray mass spectrometry is used to give both a qualitative and quantitative measure of ion binding with cross validation by solution 1H NMR, demonstrating it is possible to utilize gas-phase electrospray mass spectrometry continuous variation data to deduce binding stoichiometries in solutions where artifacts and nonspecific complexes are also observed.

Graphical abstract: Quantification of ion binding using electrospray mass spectrometry

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Publication details

The article was received on 10 Sep 2013, accepted on 23 Oct 2013 and first published on 06 Jan 2014


Article type: Communication
DOI: 10.1039/C3QI00037K
Citation: Inorg. Chem. Front., 2014,1, 49-52
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    Quantification of ion binding using electrospray mass spectrometry

    J. S. Mathieson, G. J. T. Cooper, M. D. Symes and L. Cronin, Inorg. Chem. Front., 2014, 1, 49
    DOI: 10.1039/C3QI00037K

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