Jump to main content
Jump to site search

Issue 1, 2014
Previous Article Next Article

Quantification of ion binding using electrospray mass spectrometry

Author affiliations

Abstract

Mass spectrometry has predominately been used as a qualitative tool in the analysis of complexes with quantitative studies being difficult to validate. Here, we present a method where electrospray mass spectrometry is used to give both a qualitative and quantitative measure of ion binding with cross validation by solution 1H NMR, demonstrating it is possible to utilize gas-phase electrospray mass spectrometry continuous variation data to deduce binding stoichiometries in solutions where artifacts and nonspecific complexes are also observed.

Graphical abstract: Quantification of ion binding using electrospray mass spectrometry

Back to tab navigation

Supplementary files

Publication details

The article was received on 10 Sep 2013, accepted on 23 Oct 2013 and first published on 06 Jan 2014


Article type: Communication
DOI: 10.1039/C3QI00037K
Citation: Inorg. Chem. Front., 2014,1, 49-52
  •   Request permissions

    Quantification of ion binding using electrospray mass spectrometry

    J. S. Mathieson, G. J. T. Cooper, M. D. Symes and L. Cronin, Inorg. Chem. Front., 2014, 1, 49
    DOI: 10.1039/C3QI00037K

Search articles by author

Spotlight

Advertisements