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Issue 6, 2014
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A family of [Ni8] cages templated by μ6-peroxide from dioxygen activation

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Abstract

A family of exceptionally thermally stable [Ni8] cages is reported, each being templated by a rare η336-O22− species produced by dioxygen activation, where the reducing agent for the O2 reduction appears to be the ligand used in the reaction mixtures, which was found within the nickel cages in its oxidized form.

Graphical abstract: A family of [Ni8] cages templated by μ6-peroxide from dioxygen activation

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Publication details

The article was received on 02 Apr 2014, accepted on 12 May 2014 and first published on 13 May 2014


Article type: Paper
DOI: 10.1039/C4QI00048J
Citation: Inorg. Chem. Front., 2014,1, 487-494
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    A family of [Ni8] cages templated by μ6-peroxide from dioxygen activation

    A. Perivolaris, C. C. Stoumpos, J. Karpinska, A. G. Ryder, J. M. Frost, K. Mason, A. Prescimone, A. M. Z. Slawin, V. G. Kessler, J. S. Mathieson, L. Cronin, E. K. Brechin and G. S. Papaefstathiou, Inorg. Chem. Front., 2014, 1, 487
    DOI: 10.1039/C4QI00048J

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