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Issue 21, 2014
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Network formation mechanisms in conjugated microporous polymers

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Abstract

We discuss in detail the mechanism of formation of a highly microporous polymer, CMP-1, formed mainly via Sonogashira–Hagihara coupling. We demonstrate how the microporosity evolves with time, and discuss the importance of alkyne homo-coupling on the microporosity.

Graphical abstract: Network formation mechanisms in conjugated microporous polymers

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Publication details

The article was received on 08 May 2014, accepted on 20 Jul 2014 and first published on 21 Jul 2014


Article type: Paper
DOI: 10.1039/C4PY00647J
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Citation: Polym. Chem., 2014,5, 6325-6333
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    Network formation mechanisms in conjugated microporous polymers

    A. Laybourn, R. Dawson, R. Clowes, T. Hasell, A. I. Cooper, Y. Z. Khimyak and D. J. Adams, Polym. Chem., 2014, 5, 6325
    DOI: 10.1039/C4PY00647J

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