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Issue 5, 2014
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Photochemical ligand ejection from non-sterically promoted Ru(II)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes

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Abstract

Complexes of the form [Ru(diimine)2(btz)]2+ (btz = 1,1′-dibenzyl-4,4′-bi-1,2,3-triazolyl) are observed to undergo photochemical ejection of the btz ligand in the absence of any promotion through steric congestion to generate cis-bis(solvent) complexes [Ru(diimine)2(solvent)2]2+.

Graphical abstract: Photochemical ligand ejection from non-sterically promoted Ru(ii)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes

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Publication details

The article was received on 23 Dec 2013, accepted on 19 Mar 2014 and first published on 20 Mar 2014


Article type: Communication
DOI: 10.1039/C3PP50437A
Citation: Photochem. Photobiol. Sci., 2014,13, 735-738
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    Photochemical ligand ejection from non-sterically promoted Ru(II)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes

    C. E. Welby, G. K. Armitage, H. Bartley, A. Sinopoli, B. S. Uppal and P. I. P. Elliott, Photochem. Photobiol. Sci., 2014, 13, 735
    DOI: 10.1039/C3PP50437A

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