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Issue 42, 2014
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Decarboxylative allylations of ester enolate equivalents

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Abstract

A variety of ester enolate equivalents are generated in situ and undergo α-allylation in high yields via palladium-catalyzed decarboxylative allylation. The transformations are complete within very short reaction times under ambient conditions. Synthesis of α-allylated acyl derivatives provides access to other carboxylic acid and alcohol derivatives via acyl group substitution or reduction.

Graphical abstract: Decarboxylative allylations of ester enolate equivalents

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Publication details

The article was received on 15 Aug 2014, accepted on 12 Sep 2014 and first published on 15 Sep 2014


Article type: Communication
DOI: 10.1039/C4OB01752H
Citation: Org. Biomol. Chem., 2014,12, 8386-8389
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    Decarboxylative allylations of ester enolate equivalents

    Y. Ariyarathna and J. A. Tunge, Org. Biomol. Chem., 2014, 12, 8386
    DOI: 10.1039/C4OB01752H

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