Issue 46, 2014
From the journal:

Organic & Biomolecular Chemistry

Rhodium(iii)-catalyzed C–H alkynylation of azomethine ylides under mild conditions†

Xueyun Zhang,ab   Zisong Qi,b   Jian Gao*a  and  Xingwei Li*b  

* Corresponding authors

a School of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Ji'nan 250353, China

b Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
E-mail: xwli@dicp.ac.cn

Abstract

Rh(III)-catalyzed efficient C–H alkynylation of azomethine imines with alkynylated hypervalent iodine is developed under mild conditions. A broad scope of azomethine imines and alkyne substrates is established. The azomethine acts as a masked aldehyde and circumvents its poor directing effect.

Graphical abstract: Rhodium(iii)-catalyzed C–H alkynylation of azomethine ylides under mild conditions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4OB01596G
Article type
Communication
Submitted
28 Jul 2014
Accepted
30 Sep 2014
First published
30 Sep 2014

Org. Biomol. Chem., 2014,12, 9329-9332

Author version available

Download author version (PDF)

Permissions

Request permissions

Rhodium(III)-catalyzed C–H alkynylation of azomethine ylides under mild conditions

X. Zhang, Z. Qi, J. Gao and X. Li, Org. Biomol. Chem., 2014, 12, 9329 DOI: 10.1039/C4OB01596G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements