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Issue 38, 2014
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A concise synthesis of (alkynyl)(trifluoromethyl)sulfanes via a bismuth(III)-promoted reaction of trimethyl(alkynyl)silane with trifluoromethanesulfanylamide

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Abstract

A bismuth(III)-promoted reaction of trimethyl(alkynyl)silanes with trifluoromethanesulfanylamide is developed, giving rise to (alkynyl)(trifluoromethyl)sulfanes in good yields.

Graphical abstract: A concise synthesis of (alkynyl)(trifluoromethyl)sulfanes via a bismuth(iii)-promoted reaction of trimethyl(alkynyl)silane with trifluoromethanesulfanylamide

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Publication details

The article was received on 10 Jul 2014, accepted on 06 Aug 2014 and first published on 06 Aug 2014


Article type: Paper
DOI: 10.1039/C4OB01451K
Citation: Org. Biomol. Chem., 2014,12, 7629-7633
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    A concise synthesis of (alkynyl)(trifluoromethyl)sulfanes via a bismuth(III)-promoted reaction of trimethyl(alkynyl)silane with trifluoromethanesulfanylamide

    J. Sheng and J. Wu, Org. Biomol. Chem., 2014, 12, 7629
    DOI: 10.1039/C4OB01451K

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