Issue 38, 2014

A concise synthesis of (alkynyl)(trifluoromethyl)sulfanes via a bismuth(iii)-promoted reaction of trimethyl(alkynyl)silane with trifluoromethanesulfanylamide

Abstract

A bismuth(III)-promoted reaction of trimethyl(alkynyl)silanes with trifluoromethanesulfanylamide is developed, giving rise to (alkynyl)(trifluoromethyl)sulfanes in good yields.

Graphical abstract: A concise synthesis of (alkynyl)(trifluoromethyl)sulfanes via a bismuth(iii)-promoted reaction of trimethyl(alkynyl)silane with trifluoromethanesulfanylamide

Supplementary files

Article information

Article type
Paper
Submitted
10 Jul 2014
Accepted
06 Aug 2014
First published
06 Aug 2014

Org. Biomol. Chem., 2014,12, 7629-7633

A concise synthesis of (alkynyl)(trifluoromethyl)sulfanes via a bismuth(III)-promoted reaction of trimethyl(alkynyl)silane with trifluoromethanesulfanylamide

J. Sheng and J. Wu, Org. Biomol. Chem., 2014, 12, 7629 DOI: 10.1039/C4OB01451K

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