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Issue 36, 2014
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A facile manganese dioxide mediated oxidation of primary benzylamines to benzamides

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Abstract

A high yielding manganese dioxide mediated oxidation of benzylamines to the corresponding amides has been developed under mild reaction conditions. The mechanism for the conversion has been explored by 1H NMR spectroscopy and the role of both manganese dioxide and molecular sieves in the reaction elucidated.

Graphical abstract: A facile manganese dioxide mediated oxidation of primary benzylamines to benzamides

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Publication details

The article was received on 05 Jun 2014, accepted on 29 Jul 2014 and first published on 30 Jul 2014


Article type: Paper
DOI: 10.1039/C4OB01166J
Author version available: Download Author version (PDF)
Citation: Org. Biomol. Chem., 2014,12, 7150-7158
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    A facile manganese dioxide mediated oxidation of primary benzylamines to benzamides

    A. Poeschl and D. M. Mountford, Org. Biomol. Chem., 2014, 12, 7150
    DOI: 10.1039/C4OB01166J

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