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Issue 38, 2014
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A new approach to asymmetric synthesis of infectocaryone

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Abstract

A useful and flexible strategy for synthesis of (−)- and (+)-infectocaryone from commercial sugars is developed. The key step of the synthesis is a new-type Diels–Alder reaction with good chemoselectivity and stereoselectivity, in which a mixture of alkene regioisomers in a dynamic equilibrium is employed as chiral dienophiles for the first time.

Graphical abstract: A new approach to asymmetric synthesis of infectocaryone

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Publication details

The article was received on 05 Jun 2014, accepted on 06 Aug 2014 and first published on 06 Aug 2014


Article type: Paper
DOI: 10.1039/C4OB01162G
Citation: Org. Biomol. Chem., 2014,12, 7603-7611
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    A new approach to asymmetric synthesis of infectocaryone

    X. Liu, L. Hu, X. Liu, J. Jia, L. Jiang, J. Lin and X. Chen, Org. Biomol. Chem., 2014, 12, 7603
    DOI: 10.1039/C4OB01162G

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