Issue 24, 2014

A Pd-catalyzed cascade reaction of N–H insertion and oxidative dehydrogenative aromatization: a new entry to 2-amino-phenols

Abstract

A palladium-catalyzed cascade reaction of N–H insertion (NHI) and oxidative dehydrogenative aromatization (ODA) has been developed, which affords a straightforward and efficient way to access the carbazole precursors (2-arylamino-phenols) as well as to prepare 2-alkylamino-phenols from non-aromatic substrates.

Graphical abstract: A Pd-catalyzed cascade reaction of N–H insertion and oxidative dehydrogenative aromatization: a new entry to 2-amino-phenols

Supplementary files

Article information

Article type
Communication
Submitted
27 Mar 2014
Accepted
29 Apr 2014
First published
29 Apr 2014

Org. Biomol. Chem., 2014,12, 4084-4088

Author version available

A Pd-catalyzed cascade reaction of N–H insertion and oxidative dehydrogenative aromatization: a new entry to 2-amino-phenols

D. Ding, X. Lv, J. Li, L. Qiu, G. Xu and J. Sun, Org. Biomol. Chem., 2014, 12, 4084 DOI: 10.1039/C4OB00652F

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