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Issue 22, 2014
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Rh(III)-catalyzed regioselective hydroarylation of alkynes via directed C–H functionalization of pyridines

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Abstract

Rh(III)-catalyzed C-3 selective alkenylation of pyridine derivatives via hydroarylation of alkynes has been developed. The reaction shows high regioselectivity, high yield and good functional group tolerance, providing a convenient strategy for the synthesis of trisubstituted (pyridin-3-yl)alkenes.

Graphical abstract: Rh(iii)-catalyzed regioselective hydroarylation of alkynes via directed C–H functionalization of pyridines

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Publication details

The article was received on 22 Mar 2014, accepted on 09 Apr 2014 and first published on 10 Apr 2014


Article type: Communication
DOI: 10.1039/C4OB00612G
Citation: Org. Biomol. Chem., 2014,12, 3594-3597
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    Rh(III)-catalyzed regioselective hydroarylation of alkynes via directed C–H functionalization of pyridines

    Z. Qian, J. Zhou, B. Li, F. Hu and B. Shi, Org. Biomol. Chem., 2014, 12, 3594
    DOI: 10.1039/C4OB00612G

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