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Issue 26, 2014
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Chiral Brønsted acid catalyzed enantioselective intermolecular allylic aminations

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Abstract

This paper describes an enantioselective intermolecular allylic amination catalyzed by a chiral Brønsted acid via a possible chiral contact ion pair intermediate. A variety of symmetrical or unsymmetrical allylic alcohols can be smoothly aminated to afford the desired products in moderate to high yields with good enantioselectivities and/or regioselectivities.

Graphical abstract: Chiral Brønsted acid catalyzed enantioselective intermolecular allylic aminations

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Publication details

The article was received on 10 Mar 2014, accepted on 23 Apr 2014 and first published on 24 Apr 2014


Article type: Communication
DOI: 10.1039/C4OB00526K
Citation: Org. Biomol. Chem., 2014,12, 4590-4593
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    Chiral Brønsted acid catalyzed enantioselective intermolecular allylic aminations

    M. Zhuang and H. Du, Org. Biomol. Chem., 2014, 12, 4590
    DOI: 10.1039/C4OB00526K

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