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Issue 21, 2014
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Ring-closing metathesis for the synthesis of a molecular gyrotop

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Abstract

Macrocage molecules with a bridged phenylene rotor have been synthesized as molecular gyrotops, whose cages were constructed by ring-closing metathesis (RCM) of bis(trialkenylsilyl)benzenes. An analysis of the yields of the products in the RCM reaction under various temperature conditions revealed that the desired cage, i.e., a molecular gyrotop, was produced in good yield under reflux, indicating that the cage is a thermodynamically controlled product.

Graphical abstract: Ring-closing metathesis for the synthesis of a molecular gyrotop

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Publication details

The article was received on 01 Mar 2014, accepted on 27 Mar 2014 and first published on 17 Apr 2014


Article type: Communication
DOI: 10.1039/C4OB00470A
Author version available: Download Author version (PDF)
Citation: Org. Biomol. Chem., 2014,12, 3354-3357
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    Ring-closing metathesis for the synthesis of a molecular gyrotop

    W. Setaka, S. Higa and K. Yamaguchi, Org. Biomol. Chem., 2014, 12, 3354
    DOI: 10.1039/C4OB00470A

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