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Issue 24, 2014
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Gold-catalyzed tandem Diels–Alder reactions of enynals/enynones with alkenes: generation and trapping of cyclic o-QDMs

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Abstract

An efficient gold-catalyzed method to generate the highly reactive cyclic o-QDM species from the enynal/enynone and alkene is reported. This method allows rapid access to a variety of structurally unique propeller-like products through tandem Diels–Alder reactions.

Graphical abstract: Gold-catalyzed tandem Diels–Alder reactions of enynals/enynones with alkenes: generation and trapping of cyclic o-QDMs

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Publication details

The article was received on 12 Feb 2014, accepted on 18 Feb 2014 and first published on 18 Feb 2014


Article type: Paper
DOI: 10.1039/C4OB00321G
Citation: Org. Biomol. Chem., 2014,12, 4104-4111
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    Gold-catalyzed tandem Diels–Alder reactions of enynals/enynones with alkenes: generation and trapping of cyclic o-QDMs

    S. Zhu, L. Hu and H. Jiang, Org. Biomol. Chem., 2014, 12, 4104
    DOI: 10.1039/C4OB00321G

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