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Issue 18, 2014
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Triptycene-derived macrotricyclic polyether containing an anthracene unit as a powerful host for 1,2-bis(pyridium)ethane, diquat and 2,7-diazapyrenium salt

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Abstract

Triptycene-derived macrotricyclic polyether containing an anthracene unit is a powerful host for 1,2-bis(pyridium)ethane, diquat and 2,7-diazapyrenium salt with association constants of the 1 : 1 complexes at >105 M−1. Crystal structures showed that π–π stacking interactions between the host and the guests play an important role in the formation of the stable complexes.

Graphical abstract: Triptycene-derived macrotricyclic polyether containing an anthracene unit as a powerful host for 1,2-bis(pyridium)ethane, diquat and 2,7-diazapyrenium salt

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Publication details

The article was received on 11 Feb 2014, accepted on 25 Feb 2014 and first published on 25 Feb 2014


Article type: Communication
DOI: 10.1039/C4OB00310A
Citation: Org. Biomol. Chem., 2014,12, 2850-2853
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    Triptycene-derived macrotricyclic polyether containing an anthracene unit as a powerful host for 1,2-bis(pyridium)ethane, diquat and 2,7-diazapyrenium salt

    Y. Gu, F. Zeng, Z. Meng and C. Chen, Org. Biomol. Chem., 2014, 12, 2850
    DOI: 10.1039/C4OB00310A

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