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Issue 24, 2014
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Zinc mediated allylations of chlorosilanes promoted by ultrasound: Synthesis of novel constrained sila amino acids

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Abstract

A simple, fast and efficient method for allylation and propargylation of chlorosilanes through zinc mediation and ultrasound promotion is reported. As a direct application of the resulting bis-allylsilanes, three novel, constrained sila amino acids are prepared for the first time. The design and synthesis of the constrained sila analogue of GABA (γ-amino butyric acid) is a highlight of this work.

Graphical abstract: Zinc mediated allylations of chlorosilanes promoted by ultrasound: Synthesis of novel constrained sila amino acids

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Publication details

The article was received on 08 Feb 2014, accepted on 27 Mar 2014 and first published on 27 Mar 2014


Article type: Communication
DOI: 10.1039/C4OB00294F
Citation: Org. Biomol. Chem., 2014,12, 4093-4097
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    Zinc mediated allylations of chlorosilanes promoted by ultrasound: Synthesis of novel constrained sila amino acids

    R. Ramesh and D. S. Reddy, Org. Biomol. Chem., 2014, 12, 4093
    DOI: 10.1039/C4OB00294F

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