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Regioselective 1,4- over 1,2-addition of 3,3-bis(silyl) allyloxy lithium to enals, enones and enoates. The remarkable α-effect of silicon

Xincui Ye,a   Xianwei Sun,a   Zhenggang Huang,a   Na Yang,b   Zhishan Su,b   Changwei Hub and   Zhenlei Song*ac  
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a
Key laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry, West China School of Pharmacy, Sichuan University, Chengdu, China
E-mail: zhenleisong@scu.edu.cn
b
Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry Sichuan University, Chengdu, China
c
State Key Laboratory of Biotherapy, West China Hospital, Sichuan University, Chengdu, China
Org. Biomol. Chem., 2014,12, 3021-3025

DOI: 10.1039/C4OB00139G
Received 19 Jan 2014, Accepted 06 Mar 2014
First published online 06 Mar 2014
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