Issue 14, 2014

Metal free oxidative coupling of aryl formamides with alcohols for the synthesis of carbamates

Abstract

A direct transformation of N-aryl formamides to the corresponding carbamates via the formation of isocyanate intermediates is achieved in good yields using hypervalent iodine as an oxidant.

Graphical abstract: Metal free oxidative coupling of aryl formamides with alcohols for the synthesis of carbamates

Supplementary files

Article information

Article type
Communication
Submitted
09 Jan 2014
Accepted
13 Feb 2014
First published
13 Feb 2014

Org. Biomol. Chem., 2014,12, 2172-2175

Author version available

Metal free oxidative coupling of aryl formamides with alcohols for the synthesis of carbamates

N. V. Reddy, K. R. Prasad, P. S. Reddy, M. Lakshmi Kantam and K. R. Reddy, Org. Biomol. Chem., 2014, 12, 2172 DOI: 10.1039/C4OB00066H

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