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β-Amyrin synthase from Euphorbia tirucalli. Steric bulk, not the π-electrons of Phe, at position 474 has a key role in affording the correct folding of the substrate to complete the normal polycyclization cascade
Org. Biomol. Chem., 2014, Accepted Manuscript
Received 09 Jan 2014, Accepted 14 Feb 2014
First published online 17 Feb 2014
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